کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9769856 | 1501933 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Monosaccharide optical sensor based on ruthenium(II)-bis(bipyridine) of 4-nitrophenyl-di-2-pyridyl ketone hydrazone (dpknph), [Ru(bipy)2(dpknph)]Cl2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Monosaccharide optical sensor based on ruthenium(II)-bis(bipyridine) of 4-nitrophenyl-di-2-pyridyl ketone hydrazone (dpknph), [Ru(bipy)2(dpknph)]Cl2 Monosaccharide optical sensor based on ruthenium(II)-bis(bipyridine) of 4-nitrophenyl-di-2-pyridyl ketone hydrazone (dpknph), [Ru(bipy)2(dpknph)]Cl2](/preview/png/9769856.png)
چکیده انگلیسی
Optical measurements on [Ru(bipy)2(dpknph)]Cl2, where bipy is 2,2â²-bipyridine and dpknph is di-2-pyridyl ketone p-nitrophenyl hydrazone, in polar dimethyl sulfoxide (DMSO) in the presence and absence of NaBH4/NaBF4 confirmed the reversible interconversion between the high- and low-energy electronic states of [Ru(bipy)2(dpknph)]Cl2 at 576 and 412Â nm, respectively. The addition of an external stimulus improves the optosensing behavior of [Ru(bipy)2(dpknph)]Cl2 because of the disturbance of the equilibrium distribution of the electronic states. Optical measurements on [Ru(bipy)2(dpknph)]Cl2 in the presence and absence of NaBH4 reveal high sensitivity of the electronic states of [Ru(bipy)2(dpknph)]Cl2 to slight variations in the concentration of monosaccharide, glucose and fructose in this study. Monosaccharide in concentration as low as 1Ã10â9Â M can be detected and determined using [Ru(bipy)2(dpknph)]Cl2 in DMSO in the presence and absence of NaBH4. In the presence of NaBH4, the system shows higher sensitivity toward glucose.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 753, Issues 1â3, 28 October 2005, Pages 35-39
Journal: Journal of Molecular Structure - Volume 753, Issues 1â3, 28 October 2005, Pages 35-39
نویسندگان
Mohammed Bakir, Colin Gyles,