کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9812597 | 1518116 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Study of the electrodeposition of rhenium thin films by electrochemical quartz microbalance and X-ray photoelectron spectroscopy
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Rhenium thin films were prepared by electrodeposition from an aqueous solution containing 0.1 M Na2SO4+H2SO4, pH 2 in presence of y mM HReO4. As substrates polycrystalline gold (y=0.75 mM HReO4) and monocrystalline n-Si(100) (y=40 mM HReO4) were used. The electrochemical growth of rhenium was studied by cyclic voltammetry and electrochemical quartz microbalance on gold electrodes. The results found in the potential region before the hydrogen evolution reaction (her) showed that ReO3, ReO2 and Re2O3 with different hydration grades can be formed. In the potential region where the her is occurring, either on gold or n-Si(100) the electrodeposition of metallic rhenium takes place. On both substrates, rhenium films were formed by electrolysis at constant potential and X-ray photoelectron spectroscopy technique was used to characterise these deposits. It was concluded that the electrodeposited films were of metallic rhenium and only the uppermost atomic layer contained rhenium oxide species.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 483, Issues 1â2, 1 July 2005, Pages 50-59
Journal: Thin Solid Films - Volume 483, Issues 1â2, 1 July 2005, Pages 50-59
نویسندگان
R. Schrebler, P. Cury, C. Suárez, E. Muñoz, F. Vera, R. Córdova, H. Gómez, J.R. Ramos-Barrado, D. Leinen, E.A. Dalchiele,