کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9812950 1518123 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Infrared and ultra violet-visible spectroscopic investigation of plasma polymerized N,N,3,5-tetramethylaniline thin films
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Infrared and ultra violet-visible spectroscopic investigation of plasma polymerized N,N,3,5-tetramethylaniline thin films
چکیده انگلیسی
Plasma polymerized N,N,3,5-tetramethylaniline (PPTMA) thin films were deposited on to glass substrates at room temperature by a capacitively coupled parallel plate reactor. The as-grown and heat-treated thin films of about 400 nm thick were characterized by infrared (IR) and ultraviolet-visible (UV-Vis) spectrometry. The structural analyses reveal that PPTMA thin films are formed with certain amount of conjugation, which modifies on heat treatment. From the UV-Vis absorption spectra, allowed direct transition (Eqd) and indirect transition (Eqi) energy gaps are determined to be 2.80 and 1.56 eV, respectively. While Eqd increases a little, Eqi decreases, on heat treatment of PPTMA. The calculated values of B for all the samples indicate an increase in structural order/conjugation in PPTMA thin films on heat treatment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 474, Issues 1–2, 1 March 2005, Pages 14-18
نویسندگان
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