کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1299477 | 1498743 | 2014 | 21 صفحه PDF | دانلود رایگان |
• There are numerous N- and C-coordinated coordination modes of 1,2,3-triazole ligands.
• The N3 coordination mode of 1,2,3-triazoles shows multiple catalytic activities.
• Deprotonated C- or N-bonded triazole complexes show excellent catalytic properties.
• 1,2,3-Triazole complexes compare with imidazole and imidazolium ones in catalysis.
• 1,2,3-Triazole ligands combined with “biometals” largely provide “green” catalysis.
A short overview of the multiple coordination modes of 1,2,3-triazole- and related transition-metal complexes are provided, then the implication of and catalysis with transition-metal-1,2,3-triazole complexes are detailed with Mn, Fe, Ni, Cu, Ru, Rh, Ir, Pd, and Au catalysts including various ligand coordination modes and mechanistic features.
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Journal: Coordination Chemistry Reviews - Volume 272, 1 August 2014, Pages 145–165