کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1665684 | 1518052 | 2014 | 6 صفحه PDF | دانلود رایگان |
• Ga-doped ZnO films were deposited using radiofrequency magnetron sputtering.
• Abnormal grain growth was reproduced in lightly doped zinc oxide film.
• Grains grew abnormally with polarity flipping.
• Spatial fluctuations in compositions of gallium may trigger polarity flipping.
The effect of crystalline polarity on the microstructure of gallium-doped zinc oxide (GZO) deposited using magnetron sputtering onto glass substrates was investigated. X-ray photoelectron spectroscopy was used to determine the crystalline polarity of c-axis textured GZO films. Grains whose radii were more than 1 μm grew abnormally in 0.2 mol% doped GZO when the film was thicker than ~ 1 μm, and the radius of the grains was much smaller than 100 nm in the heavily (i.e., 4 mol%) doped GZO, regardless of the film thickness. Such abnormal growth of the grains in the 0.2 mol% doped GZO films coincided with a change in the crystalline polarity: the surfaces of unusually large GZO grains were terminated with the (0001¯) face, and those of normal GZO grains were terminated with the (0001) face. The results indicated that polarity flipping is a very important event for controlling the texture of doped zinc oxide films.
Journal: Thin Solid Films - Volume 552, 3 February 2014, Pages 56–61