کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1667301 1008849 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Growth mode transition of atomic layer deposited Al2O3 on porous TiO2 electrodes of dye-sensitized solar cells
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Growth mode transition of atomic layer deposited Al2O3 on porous TiO2 electrodes of dye-sensitized solar cells
چکیده انگلیسی

This study investigates the growth behavior of atomic-layer-deposited (ALD) Al2O3 overlayers on porous TiO2 electrodes, which comprise an anatase nanoparticle layer and a rutile particle layer, for optimizing dye-sensitized solar cells. The growth mode of the ALD Al2O3 overlayers changes from island growth to layer-by-layer growth during the first few ALD reaction cycles, and the growth mode transition is much more pronounced for the anatase electrode layer. The transition is likely a result of the reduction in the contractive lattice strain of the TiO2 nanoparticles. The lattice strain in the hydroxylated TiO2 nanoparticles is progressively reduced during the ALD Al2O3 deposition, resulting in the growth mode transition.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 520, Issue 6, 1 January 2012, Pages 1745–1750
نویسندگان
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