کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1668635 | 1008872 | 2011 | 4 صفحه PDF | دانلود رایگان |

Epitaxial ZnO/Mg0.1Zn0.9O (MZO) nano-scale multilayer thin films were prepared on Al2O3 (0001) substrates by pulsed laser deposition. The ZnO/MZO multilayer thin films were grown by stacking alternate layers of ZnO and Mg0.1Zn0.9O with a laser fluence, repetition rate, substrate temperature and oxygen partial pressure of 3 J/cm2, 5 Hz, 600 °C and 3.8 × 10− 7 Pa, respectively. The thickness of an individual ZnO layer was maintained at 3 nm, whereas that of the MZO layers was varied from 3 nm to 15 nm. Cross-sectional transmission electron microscopy revealed alternating layers of bright and dark contrast, indicating the formation of a ZnO/MZO multilayer. X-ray diffraction results showed that multilayer thin films were epitaxially grown as a hexagonal wurzite phase with orientation relationship of (0001)[101¯1]multilayer||(0001)[101¯1]substrate. The 2θ value of the (0002) peak of the ZnO/MZO multilayer thin films increased from 34.30° to 34.71°, indicating that Mg is replaced with Zn in the hexagonal lattice in the MZO of ZnO/MZO multilayer. UV–visible spectroscopy showed a systematic increase in the band gap of the ZnO/MZO multilayer thin films from 3.34 eV to 3.70 eV with increasing MZO layer thickness, which suggests that the band gap energy of a ZnO/MZO multilayer thin film can be controlled by varying the thickness of each constituent layer.
Journal: Thin Solid Films - Volume 519, Issue 13, 29 April 2011, Pages 4282–4285