کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1675940 1518088 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ordering and dewetting in spin-coated films of a liquid crystalline main chain polymer
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Ordering and dewetting in spin-coated films of a liquid crystalline main chain polymer
چکیده انگلیسی

The ordering of spin-coated films of a main-chain smectic liquid crystalline polymer with an azobenzene group connected by flexible spacers to a phenyl malonate unit has been studied as a function of film thickness using scanning force microscopy and UV/Vis spectroscopy. Already the as-prepared films are characterized by a significant out-of-plane orientation of the azobenzene groups. Annealing of films thicker than 7 nm results in aggregation and homeotropical alignment of azobenzene groups forming smectic layers parallel to the substrate. An optically isotropic mesophase was found upon annealing in the temperature range of smectic mesophase.Films thinner than the bilayer thickness of 7 nm exhibit a completely different behavior, whereby spin-coating results in a spontaneously homeotropic alignment of the azobenzene units. A subsequent annealing generates a structure of holes and rims. Within the holes a polymer monolayer remains, planarly aligned to substrate.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 514, Issues 1–2, 30 August 2006, Pages 165–173
نویسندگان
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