Resolving original signatures from a sea of overprint — The geochemistry of the Gungri Shale (Upper Permian, Spiti Valley, India)

The geochemistry of black shales can faithfully record paleoenvironmental conditions. However, the original geochemical signatures are obscured by post-depositional events such as diagenesis and weathering. Resolving the relative influence of these processes on the geochemistry of shales requires a combination of geochemical and chemometric (chemical statistics) approaches to data analysis that identify the sources of variance in major and trace element geochemistry. The Permian Gungri Shale (Kuling Group) at Attargoo (Spiti Valley, Himachal Pradesh, India) is a gray to black shale capped, unconformably by an iron-rich pebble-sand layer (“ferruginous layer”) marking, ostensibly, the Permian–Triassic boundary. High resolution analysis of the Gungri at Attargoo (~ 3 cm intervals) reveals a geochemical record complicated by low-grade metamorphism/diagenesis and modern weathering. Using multivariate chemometric techniques (e.g., Principal Component Analysis) we identified variance in the geochemical record associated with the original detrital and depositional conditions. We also identified 4 beds within the Gungri that mark “depositional events” which may correlate to those identified in other PT sections (e.g., Guryul Ravine, Kashmir). Identification of sources of variance allowed us to identify geochemical signatures that can be used for paleooceanographic reconstruction. The Attargoo section records a sequence of discrete events including transient iron-enrichments attributed to euxinic depositional conditions and late diagenetic formation of siderite and regression condensation surfaces associated with pulsed transgression–regression towards the uppermost Permian. Our results show that chemometric analysis of geochemical data enables the resolution of paleoenvironmental conditions in shales impacted by post-depositional alteration.

► The Gungri Shale at Attargoo has not been impacted by K2O metasomatism
► Iron-enrichments occur in several beds up to 30 cm below the Permian–Triassic boundary
► Paleoenvironmental indicators such as Ce-anomaly do not appear affected by post-depositional alteration
► Event strata in the Gungri Shale at Attargoo can be resolved using a combination of geochemical and statistical approaches