The basaltic to trachydacitic upper Diliman Tuff in Manila: Petrogenesis and comparison with deposits from Taal and Laguna Calderas

The basaltic to trachydacitic (50–65 wt.% SiO2) upper Diliman Tuff is the youngest deposit of a sequence of tuffaceous deposits in Metro Manila. The deposit is located north of Taal Caldera and northwest of Laguna Caldera, which are both within the Southwest Luzon Volcanic Field. Chemical variations in the pumice fragments within the upper Diliman Tuff include medium-K basalt to basaltic andesite, high-K basaltic andesite to andesite and trachyandesite to trachydacite. Magma mixing/mingling is ubiquitous and is shown by banding textures in some pumice fragments, considerable range in groundmass glass composition (54 to 65 wt.% SiO2) in a single pumice fragment, and zoning in plagioclase phenocrysts. Simple binary mixing modeling and polytopic vector analysis were used to further evaluate magma mixing. Trace-element variations are inconsistent with the medium-K and high-K magmas being related by crystal fractionation. The medium-K basalts represent hotter intrusions, which induced small degrees of partial melting in older crystallized medium-K basaltic material within the crust to produce the high-K magmas. All melts likely differentiated in the crust but the emplaced and new basaltic intrusions originated from the mantle wedge and were generated by subduction zone processes. The volcanic source vent for the upper Diliman Tuff has not been identified. In comparisons with the deposits from adjacent Taal and Laguna Calderas it is chemically distinct with respect to both major- and trace-element concentrations.