Hafnium and neodymium isotopes and REY distribution in the truly dissolved, nanoparticulate/colloidal and suspended loads of rivers in the Amazon Basin, Brazil

Our novel results clearly show that the decoupling of the Hf and Nd isotope systems is related to incongruent weathering processes on the continent, as this decoupling can already be observed in the different Hf and Nd pools, i.e. in the particulate, the NPC-dominated dissolved and the truly dissolved load of rivers. In the Rio Negro and Rio Solimões, a strong particle size-dependent difference in Hf isotope composition is observed. Values of εHf become more radiogenic as filter poresize decreases, which can be related to the density- and size-dependent distribution of Hf-rich minerals, e.g. zircons, and their absence from the truly dissolved pool. In contrast, the Nd isotope composition of Amazonian river waters reflects that of their catchment geology. Tributaries draining the Precambrian Brazilian and Guyana shields show very unradiogenic εNd values of −19 to −25 in their dissolved load, whereas the Rio Solimões draining the Andes yields a more radiogenic εNd signal of only −7. The dissolved Nd isotope composition of the Amazon is dominated by its Andean tributaries and averages at −8. Although Nd isotope compositions are thought to not being fractionated by Earth surface processes, significant differences of 1.3-1.9 ε-units can be observed between the dissolved and suspended loads in the Amazon River and its main tributary, the Rio Solimões. In these rivers, the dissolved load is more radiogenic than the suspended sediment, which is likely due to incongruent weathering and related mineral sorting in the Andean headwaters. In contrast, the organic-rich and mineral-poor shield rivers do not show a difference between the truly dissolved, dissolved and suspended load, as the Nd in all these pools is controlled by surface- and solution-complexation and hence isotopically homogenized by continuous exchange and re-equilibration.