Chemical weathering rates of silicate-dominated lithological classes and associated liberation rates of phosphorus on the Japanese Archipelago-Implications for global scale analysis

Lithology is an important characteristic of the terrestrial surface, whose properties influence chemical weathering rates. Specifically non-silicate minerals may contribute significantly to the weathering derived fluxes from silicate-dominated lithological classes. The Japanese Archipelago consists of predominantly silicate-dominated lithologies with a high proportion of volcanics. However, the spatially explicit representation of chemical weathering rates remains difficult for such a large region, because many controlling factors on chemical weathering rates are correlated with each other. Due to the spatial heterogeneity of lithology, a multi-lithological model approach to estimate spatially explicit chemical weathering rates for unmonitored areas is applied here. To achieve this, hydrochemical data of 381 catchments are used to train a set of models, recognizing the contribution of a variety of proposed factors influencing chemical silicate rock weathering rates (CSRWR: cations plus dissolved silica flux). The monitored catchments cover ~ 44% of the Japanese Archipelago. Cation chemical weathering rates (excluding Si) are linearly correlated with CSRWR and show outliers if basic volcanics or pyroclastic flows are present due to increased silica release rates.Lithology and runoff are identified as the strongest predictors for chemical weathering rates. Temperature and gradient of slope are of less relevance for the regional scale prediction while further proposed factors like soil properties or land cover are not identified as major predictors. Latter findings are partly attributed to geodata quality, low variability of parameter values as well as spatial correlations of proposed controlling factors with lithology or runoff.The calculated average CSRWR of the Archipelago is ~ 25 t km−2 a− 1 and ranges from 5.9 to 107 t km−2 a− 1 in monitored catchments. Weathering rates per lithological class as a function of runoff can be grouped into three classes: a) pyroclastic flows showing the highest chemical weathering rates; b) alluvial deposits, mixed sediments and basic to intermediate volcanics with medium rates; and c) metamorphics, siliciclastic sediments, acid volcanics, acid plutonics and unconsolidated sediments (other than alluvial deposits), showing the lowest rates.The recognition of lithogenic sulfur would add 9.7% to CSRWR of considered catchments. Results suggest that the lithological classes acid volcanics and unconsolidated sediments contribute above average to the sulfur fluxes. Possible biases of this observation are discussed.The contribution of Ca-fluxes from non-silicate calcic minerals (named Ca-excess, Ca-fluxes in addition to silicate Ca-fluxes) is about 10% of the CSRWR on average and is attributed by a wide value range. The calculated ratio “Ca-excess to total Ca-fluxes” from chemical weathering averages around 62%, 75%, 56%, 83% and 84% for the lithological classes acid plutonics, metamorphics, siliciclastic sediments, mixed sediments and acid volcanics, respectively. This suggests a major Ca-contribution from non-silicate calcic minerals for these lithological classes.Phosphorus release from rocks due to chemical weathering is estimated to be between 1 kg P km−2 a− 1 and 390 kg P km−2 a− 1. The P-release patterns in dependence of runoff per lithological class are different from CSRWRs due to differences of applied P-content in rocks. The identified spatial P-release patterns suggest that the consideration of dynamic and spatially resolved P-release rates by chemical weathering might improve ecosystem studies. Later findings may be of importance for analysing the influence of P-release from rocks on the climate system via ecosystem functioning on geological time scales. A first application of the P-release model to the global scale suggests an annual release of 1.6 Mt P (13.8 kg P km−1 a− 1) by chemical weathering of silicate dominated lithological classes (excluding carbonate sedimentary rocks).

Research Highlights► Multi-lithological approach to estimate chemical weathering rates per lithological class. ► Estimated weathering rates depend on lithological information and environmental conditions. ► Estimation of the proportion of Ca-fluxes from non silicate minerals on total Ca-fluxes. ► Estimation of the contribution of geogenic sulfur fluxes to chemical weathering fluxes. ► Prediction of P-release by chemical weathering and application to the global scale.