کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6438404 | 1638017 | 2014 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The retention of uranium and europium onto sepiolite investigated by macroscopic, spectroscopic and modeling techniques
ترجمه فارسی عنوان
حفظ اورانیوم و یوروپیوم بر روی سپیپولیت توسط روش های ماکروسکوپیک، اسپکتروسکوپی و مدل سازی
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موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
ژئوشیمی و پترولوژی
چکیده انگلیسی
Clay minerals have been proposed for the potential retention of the high-level radioactive wastes in deep geological repositories. The retention of uranium (U(VI)) and europium (Eu(III)) onto well-characterized sepiolite was elucidated by using microscopic adsorption, spectroscopic techniques and surface complexation modeling. The results of macroscopic adsorption experiments showed that the uptake of U(VI) and Eu(III) onto sepiolite significantly increased with increasing pH 4.0-7.0, whereas the decrease adsorption of U(VI) at pHÂ >Â 7.0 and in the presence of carbonate (10â3Â mol/L) was attributed to the electrostatic repulsion. The chemical affinity of U(VI) with sepiolite was stronger than that of Eu(III) with sepiolite in terms of batch desorption tests. Based on the EXAFS spectra analysis, the interatomic distances of U-Si at â¼3.16Â Ã
was observed in U(VI)/sepiolite systems, which indicated that the inner-sphere surface species were coordinated on SiO4 tetrahedra via bidentate configuration. The U-C shell at â¼2.9Â Ã
in the presence of carbonate revealed the U(VI)-carbonate ternary complexes at sepiolite-water interface. The results from the three common surface complexation models (SCMs), including constant-capacitance model (CCM), diffuse-layer model (DLM), and triple-layer model (TLM), can give an excellent fit to the experimental data with the bidentate edge-sharing (E2, >SO2M(n â 2)+), bidentate corner-sharing (C2, (>SO)2M(OH)2(n â 4)+) and >SOMCO3(n â 3)+ inner-sphere surface complexes in ambient environments. However, the second ternary surface complex >SOCO2M(n â 1)+ was determined in the presence of carbonate. The findings presented in this study are significant toward the description and predication of fate and transport of radionuclides at the water-mineral interface in the natural environment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Geochimica et Cosmochimica Acta - Volume 140, 1 September 2014, Pages 621-643
Journal: Geochimica et Cosmochimica Acta - Volume 140, 1 September 2014, Pages 621-643
نویسندگان
Yubing Sun, Jiaxing Li, Xiangke Wang,