کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6472645 1424135 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Rapid sensing of antioxidant capacity based on electrochemiluminescence induced by electrochemically generated reactive oxygen species
ترجمه فارسی عنوان
سنجش سریع ظرفیت آنتی اکسیدانی بر اساس الکتروکوهمولومینسانس ناشی از گونه های اکسیژن واکنشی تولید شده توسط الکتروشیمیایی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی

A simple and rapid electrochemiluminescence (ECL) method for the measurement of antioxidant capacity using a portable ECL device with a screen-printed electrode is described. The ECL method is based on the luminous reaction of reactive oxygen species (ROS), luminol radicals and antioxidants. ROS are generated by the electrochemical reduction of dissolved oxygen and competitively react with the luminol and antioxidants. The ECL intensity depends on the antioxidant capacity because the radicals are neutralized by the antioxidants, suppressing the luminous reaction. An antioxidant standard curve was generated using different concentrations of known amounts of Trolox by ECL measurement and the detection limit for antioxidant capacity was found to be 0.06 mM of Trolox. An antioxidant capacity of beverages (22 types) was evaluated by comparing with the standard curve of Trolox. The time necessary for the ECL measurement of antioxidant capacity is only two minutes after combining the sample solution with luminol on a screen-printed electrode.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 222, 20 December 2016, Pages 580-586
نویسندگان
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