Magma mixing recorded in intermediate rocks associated with high-Mg andesites from the Setouchi volcanic belt, Japan: implications for Archean TTG formation

Calc-alkaline intermediate rocks are spatially and temporally associated with high-Mg andesites (HMAs, Mg#>60) in Middle Miocene Setouchi volcanic belt. The calc-alkaline rocks are characterized by higher Mg# (strongly calc-alkaline trend) than ordinary calc-alkaline rocks at equivalent silica contents. Phenocrysts in the intermediate rocks have petrographical features such as: (1) coexisting reversely and normally zoned orthopyroxene phenocrysts in single rock; (2) sieve type plagioclase in which cores are mantled by higher An%, melt inclusion-rich zone; and (3) reversely zoned amphibole phenocrysts with opacite cores. In addition, mingling textures and magmatic inclusions were observed in some rocks. These petrographic features and the mineral chemistry indicate that magma mixing was the most important process in producing the strongly calc-alkaline rocks. The core composition of normally zoned orthopyroxene phenocrysts and the mantle composition of reversely zoned orthopyroxene phenocrysts have relatively high Mg# (85-90) in maximum. Although basaltic and high-Mg andesitic magmas are candidate as possible mafic end-member magmas, basaltic magma is excluded in terms of phenocryst assemblage and bulk composition. HMA magmas are suitable mafic end-member magmas that precipitated high Mg# (∼90) orthopyroxene, whereas andesitic to dacitic magma are suitable felsic end-members. In contrast, it is difficult to produce the strongly calc-alkaline trend through fractional crystallization from a HMA magma, because it would require removal of plagioclase together with mafic minerals from the early stage of crystallization, whereas the precipitation of plagiolase is suppressed due to the high water content of HMA magmas. These results imply that Archean Mg#-rich TTGs (>45-55), which are an analog of the strongly calc-alkaline rocks in terms of chemistry and magma genesis, can be derived from magma mixing in which a HMA magma is the mafic end-member magma, rather than by fractional crystallization from a HMA magma.