کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7825960 1502981 2018 106 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Old meets new: Combination of PLA and RDRP to obtain sophisticated macromolecular architectures
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Old meets new: Combination of PLA and RDRP to obtain sophisticated macromolecular architectures
چکیده انگلیسی
This review article highlights the research focused on the synthesis of polylactide (PLA) based copolymers by combination of reversible-deactivation radical polymerization (RDRP) techniques with ring-opening polymerization (ROP) processes. In particular atom-transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization, and nitroxide-mediated polymerization (NMP) will be addressed as RDRP techniques mechanistically different from ROP in the design of various sophisticated macromolecular structures. The combination of ROP with RDRP techniques has been extensively applied to prepare PLA copolymers. We discuss the synthetic methods applicable to prepare linear and star-shaped block copolymers by use of heterofunctional initiators as well as other end functionalization methods. This is complemented with the adaption of the synthetic pathways generally used for the preparation of comb and graft copolymers, i.e., macromonomer, grafting-from and grafting-onto approaches, to the requirements of PLA-based building blocks.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Polymer Science - Volume 76, January 2018, Pages 111-150
نویسندگان
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