کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8033416 1517994 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Corrosion behaviors of TiN and Ti-Si-N (with 2.9 at.% and 5.0 at.% Si) coatings by electrochemical impedance spectroscopy
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Corrosion behaviors of TiN and Ti-Si-N (with 2.9 at.% and 5.0 at.% Si) coatings by electrochemical impedance spectroscopy
چکیده انگلیسی
TiN and Ti-Si-N (2.9 at.% and 5.0 at.% Si) coatings were fabricated on the surface of polished Si (100) wafers and stainless steel substrates by cathodic arc ion plating. The XRD results showed that the preferred orientation of the TiN crystals changed from TiN (111) to TiN (200) with an increasing silicon content. The TiN coating exhibited a polycrystalline structure with an average grain size of approximately 18 nm, while the Ti-Si-N coatings exhibited a nanocomposite structure of TiN nanocrystals embedded in amorphous Si3N4. In electrochemical impedance spectroscopy (EIS) tests, the amorphous Si3N4 phase distributed on the boundaries of the Ti-Si-N (5.0 at.% Si) coating and acted as an effective barrier layer against the penetration of the corrosion solution, which resulted in better corrosion resistance compared with TiN and the lower-Si-content Ti-Si-N coating (2.9 at.% Si). Immersion tests and surface morphology observations of the samples after corrosion were also carried out to investigate the corrosion mechanism and behaviors of TiN and Ti-Si-N composite coatings.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 616, 1 October 2016, Pages 601-607
نویسندگان
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