کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1665386 | 1518038 | 2014 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: High-rate reactive high-power impulse magnetron sputtering of Ta–O–N films with tunable composition and properties High-rate reactive high-power impulse magnetron sputtering of Ta–O–N films with tunable composition and properties](/preview/png/1665386.png)
• Controlled reactive high-power impulse magnetron sputtering was used.
• Very high deposition rates of Ta–O–N films were achieved.
• Ta–O–N films with tunable composition and properties were produced.
• Ta–O–N films with a visible-range optical band gap of 2.5 eV were prepared.
High-power impulse magnetron sputtering of a planar Ta target in various Ar + O2 + N2 gas mixtures was investigated at an average target power density close to 50 W cm− 2 during a deposition. A strongly unbalanced magnetron was driven by a pulsed dc power supply operating at the repetition frequency of 500 Hz and the average target power density of up to 2.4 kW cm− 2 in a pulse with a fixed 50 μs duration. Si(100) and glass substrates were at a floating potential, and the substrate temperatures were less than 285 °C. A pulsed reactive gas (O2 and N2) flow control made it possible to produce high-quality Ta–O–N films of various elemental compositions with high deposition rates of 97–190 nm/min. The film compositions (in at.%) were varied gradually from Ta28O71 with less than 1 at.% of H to Ta38O4N55 with 3 at.% of H. The Ta27O40N31 films with 2 at.% of H, which were produced at the 50% N2 fraction in the reactive gas flow with the highest deposition rate of 190 nm/min achieved, were nanocrystalline with an optical band gap of 2.5 eV and hardness of 8 GPa. These films with a shift of the absorption edge to 500 nm are potential candidates for application as visible-light driven photocatalysts.
Journal: Thin Solid Films - Volume 566, 1 September 2014, Pages 70–77